Alessandra also holds a very active Facebook page in which she posts personal and professional photos as well as a plethora of motivational and inspirational quotes either through captions or dedicated posts, rendering 3+ Millions fans on the social media site.
The job of Victoria's Secret model is a coveted one: The company gives its annual fashion show and the models who walk in it credit for billions of dollars in annual sales.
Beside these powerhouse models are their supportive husbands and boyfriends.
Last month at Sao Paulo Fashion Week, Ambrosio walked the Colcci runway (while pregnant! But now he's back to work, posing for Colcci's Fall/Winter 2012 campaign (Brazil's got reverse seasons).
For the ad, newly-single Ashton gets cozy with Alessandra on a bed, bravely donning double-denim while the Victoria's Secret model gets to wear some sexy print minidress.
The jokey "Two And A Half Men" star, who actually began his career as a model, has formed a close relationship with Colcci, the Brazilian fashion brand for which he's walked not one but two runway shows.
He's also posed in Colcci ad campaigns, including these July spots, with pal Alessandra Ambrosio.